Herbicide Rate |
- Applied at rates of 0.75-1.0 ppm for floating plant control near potable water intakes
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Breakdown / Inactivation |
- As an element, copper can persist indefinitely
- Precipitates out of water within a few days
- Binds to particulates in water and sediments
- Accumulates over time
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Microbial |
- Not broken down by microbes
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Adsorption |
- Adsorbs to organic materials and clay particles
- Degree of adsorption depends on acidity and alkalinity
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Photolysis |
- Not sensitive to photolysis
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Hydrolysis |
- Not sensitive to hydrolysis
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Dissipation |
- Does not disperse widely in treated waterbodies
- Limited foliar spot applications, precipitation, settling, adsorption
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Formulation |
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Liquid |
- Available in organic complex called copper chelate
- Designed to keep in solution as long as possible
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Solid |
- Copper sulfate available in crystal formulations; also called blue stone
- Copper chelate available in granulated or pelletized formulations
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Mechanism of Action
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- Classified in WSSA Resistance Grouping as Unknown
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Mode of Action |
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Contact |
- Absorbed by foliage or underwater tissues
- Does not move within the plant – contact type herbicide
- Appears to act on cell membranes or photosynthesis but how is unknown
- Cell membranes become leaky and cell contents spill out
- Without membranes, cells cannot make energy
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Plant Growth Regulator |
- Used only as herbicide for aquatic plant control applications in FWC programs
- Functions as growth inhibitor or growth regulator at lower rates
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Stewardship |
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Herbicide resistance |
- Resistance reported in blue-green algae after repeated use over decades in Minnesota
- Used occasionally for spot applications to floating plants in Florida
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Waterbody Parameters | Management Considerations |
Hydrology |
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Water depth |
- Not an issue with FWC use pattern of spot applications directly to foliage
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Water volume |
- Not an issue with FWC use pattern of spot applications directly to foliage
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Water movement |
- Not an issue with FWC use pattern of spot applications directly to foliage
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Water chemistry |
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Dissolved oxygen (DO) |
- Not an issue with FWC use pattern of spot applications directly to foliage
- May be an issue for large-scale algae control in potable water reservoirs
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pH, alkalinity, hardness |
- In waters of < 50ppm alkalinity, may be toxic to fish at rates applied to control plants
- Copper sulfate precipitates in waters with high alkalinity (> 250 ppm)
- Copper precipitation less of a concern with chelated copper formulations
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Nutrient content |
- Fast acting, but generally not an issue with the small-scale use patterns in Florida
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Water transparency |
- Color/tannic content – no issues
- Turbidity – avoid applications to highly turbid waters
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Sediment characteristics |
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Composition |
- Sand/Clay – adsorption to organic particulates and clay sediments
- Organic – adsorption to suspended organic particles
- Avoid applying pellets to deep flocculent organic sediments
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Potential for re-suspension |
- Avoid disturbing sediments when applying to shallow waters
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Plant Physiology Parameters | Management Considerations |
Plant origin / growth potential |
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Native |
- Not used to target native plants in FWC Programs
- Copper is used for short-term algae control in ponds and drinking water reservoirs
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Non-native |
- Not used to target non-native plants in FWC Programs
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Invasive
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- Water hyacinth and water lettuce
- Foliar application at .75 – 1.0 ppm
- Occasionally used near potable water intakes where other herbicides are restricted
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Plant growth stage (target/non-target) |
- Need actively growing plants for herbicide uptake
- For best results, apply to young, actively growing plants
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Plant susceptibility (target/non-target)
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- Current use in Florida is for floating plant control near potable water intakes
- More effective on young and actively growing floating plants
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Potential for regrowth (target/non-target) |
- Requires thorough wetting with spray solution
- Reinspect within 1-2 weeks for plants that may have been missed
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Climate Parameters | Management Considerations |
Weather |
Daily
- Apply when rain is not forecast
Seasonally
- Apply to actively growing plants
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Light intensity |
- Not broken down by photolysis
- Higher light intensity may equate to rapid plant growth and herbicide uptake
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Water temperature |
- No issues related to this tool
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